Heavy metal removal from waste water is essential to solve the global water crises. Transition metal oxide nanoparticles are promising candidates for these applications. Herein, Copper oxide and Tin oxide nanoparticles have been prepared via Facile and economic perception method starting from commercial precursors. The obtained nanoparticles were in flack-like shape and spherical shape for Copper oxide and Tin oxide nanoparticles, respectively. All prepared nanoparticles are in crystalline phases, where the prepared Copper oxide and Tin oxide nanoparticles were in monoclinic and tetragonal crystalline phases, respectively. The crystal size of Copper oxide and Tin oxide nanoparticles were 12 nm and 13 nm respectively. Cd and Pb ions were removed from wastewater by the obtained Copper oxide and Tin oxide nanoparticles. The adsorption processes were studied under various parameters, such as; contact time and pH values. The highest removal uptake was about ~99% of Pb ions were recorded for Copper oxide nanoparticles. This uptake process carried out after 30 min in a neutral medium (pH 7). While, Tin oxide nanoparticles removed about ~94% at the same conditions. On the other hand, Copper oxide nanoparticles removed about ~ 57% from Cd ions. This uptake process carried out after 30 min in a partially acidic medium (pH 6). While, Tin oxide nanoparticles removed about ~54% at the same conditions. Finally, it is highly recommended to use Copper oxide and Tin oxide nanoparticles as promising adsorbents for heavy metal removal applications.
| Published in | International Journal of Ecotoxicology and Ecobiology (Volume 6, Issue 1) |
| DOI | 10.11648/j.ijee.20210601.12 |
| Page(s) | 1-7 |
| Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
| Copyright |
Copyright © The Author(s), 2024. Published by Science Publishing Group |
Copper Oxide Nanoparticles, Tin Oxide Nanoparticles, Heavy Metal Removal
| [1] | X. Qu, P. J. J. J. Alvarez, Q. Li, Applications of nanotechnology in water and wastewater treatment, Water Res. 47 (2013) 3931–3946. doi: 10.1016/j.watres.2012.09.058. |
| [2] | M. A. Barakat, New trends in removing heavy metals from industrial wastewater, Arab. J. Chem. 4 (2011) 361–377. doi: 10.1016/j.arabjc.2010.07.019. |
| [3] | T. G. Chuah, A. Jumasiah, I. Azni, S. Katayon, S. Y. Thomas Choong, Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal: An overview, Desalination. 175 (2005) 305–316. doi: 10.1016/j.desal.2004.10.014. |
| [4] | T. I. Shalaby, M. F. El-Kady, A. E. H. M. Zaki, S. M. El-Kholy, Preparation and application of magnetite nanoparticles immobilized on cellulose acetate nanofibers for lead removal from polluted water, Water Sci. Technol. Water Supply. 17 (2017) 176–187. doi: 10.2166/ws.2016.124. |
| [5] | M. S. Abdullahi, Toxic effects of lead in humans: An overview, Glob. Adv. Res. J. Environ. Sci. Toxicol. 2 (2013) 157–162. http://garj.org/garjest/index.htm. |
| [6] | S. N. A. Abas, M. H. S. Ismail, M. L. Kamal, S. Izhar, Adsorption process of heavy metals by low-cost adsorbent: A review, World Appl. Sci. J. 28 (2013) 1518–1530. doi: 10.5829/idosi.wasj.2013.28.11.1874. |
| [7] | Y. Zhang, X. Duan, Chemical precipitation of heavy metals from wastewater by using the synthetical magnesium hydroxy carbonate, Water Sci. Technol. 81 (2020) 1130–1136. doi: 10.2166/wst.2020.208. |
| [8] | U.S. Environmental Protection Agency, Wastewater Technology Fact Sheet Chemical Precipitation - EPA Document # EPA 832-F-00-018, Environ. Prot. Agency. (2000) 1–7. |
| [9] | A. Bashir, L. A. Malik, S. Ahad, T. Manzoor, M. A. Bhat, G. N. Dar, A. H. Pandith, Removal of heavy metal ions from aqueous system by ion-exchange and biosorption methods, Environ. Chem. Lett. 17 (2019) 729–754. doi: 10.1007/s10311-018-00828-y. |
| [10] | T. Bakalár, M. Búgel, L. Gajdošová, Heavy metal removal using reverse osmosis, Acta Montan. Slovaca. 14 (2009) 250–253. |
| [11] | E. T. Musapatika, M. S. Onyango, O. Aoyi, Cobalt(II) removal from synthetic wastewater by adsorption on South African coal fly ash, S. Afr. J. Sci. 106 (2010) 1–7. doi: 10.4102/sajs.v106i9/10.167. |
| [12] | M. MOUSTAFA, S. ALAMRI, M. ELNOUBY, T. TAHA, M. A. ABU-SAIED, A. SHATI, M. AL-KAHTANI, S. ALRUMMAN, Hydrothermal preparation of TiO2-Ag nanoparticles and its antimicrobial performance against human pathogenic microbial cells in water, Biocell. 42 (2019) 93–97. doi: 10.32604/biocell.2018.07014. |
| [13] | R. Bhateria, R. Singh, A review on nanotechnological application of magnetic iron oxides for heavy metal removal, J. Water Process Eng. 31 (2019) 100845. doi: 10.1016/j.jwpe.2019.100845. |
| [14] | Y. J. Tu, T. S. Chan, H. W. Tu, S. L. Wang, C. F. You, C. K. Chang, Rapid and efficient removal/recovery of molybdenum onto ZnFe2O4 nanoparticles, Chemosphere. 148 (2016) 452–458. doi: 10.1016/j.chemosphere.2016.01.054. |
| [15] | S. L. Iconaru, R. Guégan, C. L. Popa, M. Motelica-Heino, C. S. Ciobanu, D. Predoi, Magnetite (Fe3O4) nanoparticles as adsorbents for As and Cu removal, Appl. Clay Sci. 134 (2016) 128–135. doi: 10.1016/j.clay.2016.08.019. |
| [16] | G. G. Bessegato, T. T. Guaraldo, J. F. de Brito, M. F. Brugnera, M. V. B. Zanoni, Achievements and Trends in Photoelectrocatalysis: from Environmental to Energy Applications, Electrocatalysis. 6 (2015) 415–441. doi: 10.1007/s12678-015-0259-9. |
| [17] | M. Ghulam, T. Hajira, S. Muhammad, A. Nasir, Synthesis and characterization of cupric oxide (CuO) nanoparticles and their application for the removal of dyes, African J. Biotechnol. 12 (2013) 6650–6660. doi: 10.5897/ajb2013.13058. |
| [18] | S. J. Davarpanah, R. Karimian, V. Goodarzi, F. Piri, Synthesis of copper (II) oxide (CuO) nanoparticles and its application as gas sensor, J. Appl. Biotechnol. Reports. 2 (2015) 329–332. |
| [19] | R. Manimaran, K. Palaniradja, N. Alagumurthi, S. Sendhilnathan, J. Hussain, Preparation and characterization of copper oxide nanofluid for heat transfer applications, Appl. Nanosci. 4 (2014) 163–167. doi: 10.1007/s13204-012-0184-7. |
| [20] | K. H. Hassan, E. R. Mahdi, Synthesis and Characterization of Copper, Iron Oxide Nanoparticles used to Remove Lead from Aquous Solution, 04 (2016) 730–738. |
| [21] | W. Zhang, B. Yang, J. Liu, X. Chen, X. Wang, C. Yang, Highly sensitive and low operating temperature SnO2 gas sensor doped by Cu and Zn two elements, Sensors Actuators, B Chem. 243 (2017) 982–989. doi: 10.1016/j.snb.2016.12.095. |
| [22] | M. H. Jo, B. R. Koo, H. J. Ahn, Accelerating F-doping in transparent conducting F-doped SnO2 films for electrochromic energy storage devices, Ceram. Int. 46 (2020) 25066–25072. doi: 10.1016/j.ceramint.2020.06.293. |
| [23] | H. Kim, H. Kim, S. Muhammad, J. H. Um, M. S. A. Sher Shah, P. J. Yoo, W. S. Yoon, Catalytic effect of reduced graphene oxide on facilitating reversible conversion reaction in SnO2 for next-generation Li rechargeable batteries, J. Power Sources. 446 (2020) 227321. doi: 10.1016/j.jpowsour.2019.227321. |
| [24] | M. Usman Hameed, S. Ullah Dar, S. Ali, S. Liu, R. Akram, Z. Wu, I. S. Butler, Facile synthesis of low-dimensional SnO2 nanostructures: An investigation of their performance and mechanism of action as anode materials for lithium-ion batteries, Phys. E Low-Dimensional Syst. Nanostructures. 91 (2017) 119–127. doi: 10.1016/j.physe.2017.04.020. |
| [25] | H. Howari, I. B. I. Tomsah, Structural, optical and ellipsometric characteristics of PVD synthesized SnO2 thin films on Pt coated silicon wafers, Optik (Stuttg). 144 (2017) 467–474. doi: 10.1016/j.ijleo.2017.05.098. |
| [26] | R. Alizadeh, R. K. Kazemi, M. R. Rezaei, Ultrafast removal of heavy metals by tin oxide nanowires as new adsorbents in solid-phase extraction technique, Int. J. Environ. Sci. Technol. 15 (2018) 1641–1648. doi: 10.1007/s13762-017-1481-1. |
| [27] | P. Sivakarthik, V. Thangaraj, K. Perumalraj, J. Balaji, Synthesis of co-doped tin oxide nanoparticles for photo catalytic degradation of synthetic organic dyes, Dig. J. Nanomater. Biostructures. 11 (2016) 935–943. |
| [28] | B. Dye, E. M. Elsayed, M. S. Elnouby, M. H. Gouda, N. A. Elessawy, S. M. H. Gouda, N. A. Elessawy, D. M. F. Santos, Effect of the morphology of tungsten oxide embedded in sodium alginate/polyvinylpyrrolidone composite beads on the photocatalytic degradation of methylene blue dye solution, Materials (Basel). 13 (2020). doi: 10.3390/MA13081905. |
| [29] | M. Shaban, M. R. Abukhadra, A. A. P. Khan, B. M. Jibali, Removal of Congo red, methylene blue and Cr(VI) ions from water using natural serpentine, J. Taiwan Inst. Chem. Eng. 82 (2018) 102–116. doi: 10.1016/j.jtice.2017.10.023. |
| [30] | K. Nithya, P. Yuvasree, N. Neelakandeswari, N. Rajasekaran, K. Uthayarani, M. Chitra, S. Sathiesh Kumar, Preparation and characterization of copper oxide nanoparticles, Int. J. ChemTech Res. 6 (2014) 2220–2222. doi: 10.5246/jcps.2020.09.057. |
| [31] | K. Y. Kumar, T. N. V. Raj, S. Archana, S. B. B. Prasad, S. Olivera, H. B. Muralidhara, SnO2 nanoparticles as effective adsorbents for the removal of cadmium and lead from aqueous solution: Adsorption mechanism and kinetic studies, J. Water Process Eng. 13 (2016) 44–52. doi: 10.1016/j.jwpe.2016.07.007. |
| [32] | O. Fadali, T. Farrag, A. Abdelbasier, Pesticides Removal from wastewater by Electrocoagulation Technique Using Stainless Steel (Ss-Ss) Plate Electrodes., Bull. Fac. Eng. Mansoura Univ. 40 (2020) 1–10. doi: 10.21608/bfemu.2020.96410. |
| [33] | D. Jiang, Y. Yang, C. Huang, M. Huang, J. Chen, T. Rao, X. Ran, Removal of the heavy metal ion nickel (II) via an adsorption method using flower globular magnesium hydroxide, J. Hazard. Mater. 373 (2019) 131–140. doi: 10.1016/j.jhazmat.2019.01.096. |
| [34] | J. Chen, N. Wang, Y. Liu, J. Zhu, J. Feng, W. Yan, Synergetic effect in a self-doping polyaniline/TiO2 composite for selective adsorption of heavy metal ions, Synth. Met. 245 (2018) 32–41. doi: 10.1016/j.synthmet.2018.08.006. |
| [35] | M. Sharma, J. Singh, S. Hazra, S. Basu, Adsorption of heavy metal ions by mesoporous ZnO and TiO2@ZnO monoliths: Adsorption and kinetic studies, Microchem. J. 145 (2019) 105–112. doi: 10.1016/j.microc.2018.10.026. |
APA Style
Ahmed Elsayed Abdelaal, Mohamed Abdel-Motaleb, Marwa Farouk El Kady, Abdel-Rahman Mustafa Hamed. (2021). Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater. International Journal of Ecotoxicology and Ecobiology, 6(1), 1-7. https://doi.org/10.11648/j.ijee.20210601.12
ACS Style
Ahmed Elsayed Abdelaal; Mohamed Abdel-Motaleb; Marwa Farouk El Kady; Abdel-Rahman Mustafa Hamed. Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater. Int. J. Ecotoxicol. Ecobiol. 2021, 6(1), 1-7. doi: 10.11648/j.ijee.20210601.12
AMA Style
Ahmed Elsayed Abdelaal, Mohamed Abdel-Motaleb, Marwa Farouk El Kady, Abdel-Rahman Mustafa Hamed. Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater. Int J Ecotoxicol Ecobiol. 2021;6(1):1-7. doi: 10.11648/j.ijee.20210601.12
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Download@article{10.11648/j.ijee.20210601.12,
author = {Ahmed Elsayed Abdelaal and Mohamed Abdel-Motaleb and Marwa Farouk El Kady and Abdel-Rahman Mustafa Hamed},
title = {Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater},
journal = {International Journal of Ecotoxicology and Ecobiology},
volume = {6},
number = {1},
pages = {1-7},
doi = {10.11648/j.ijee.20210601.12},
url = {https://doi.org/10.11648/j.ijee.20210601.12},
eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijee.20210601.12},
abstract = {Heavy metal removal from waste water is essential to solve the global water crises. Transition metal oxide nanoparticles are promising candidates for these applications. Herein, Copper oxide and Tin oxide nanoparticles have been prepared via Facile and economic perception method starting from commercial precursors. The obtained nanoparticles were in flack-like shape and spherical shape for Copper oxide and Tin oxide nanoparticles, respectively. All prepared nanoparticles are in crystalline phases, where the prepared Copper oxide and Tin oxide nanoparticles were in monoclinic and tetragonal crystalline phases, respectively. The crystal size of Copper oxide and Tin oxide nanoparticles were 12 nm and 13 nm respectively. Cd and Pb ions were removed from wastewater by the obtained Copper oxide and Tin oxide nanoparticles. The adsorption processes were studied under various parameters, such as; contact time and pH values. The highest removal uptake was about ~99% of Pb ions were recorded for Copper oxide nanoparticles. This uptake process carried out after 30 min in a neutral medium (pH 7). While, Tin oxide nanoparticles removed about ~94% at the same conditions. On the other hand, Copper oxide nanoparticles removed about ~ 57% from Cd ions. This uptake process carried out after 30 min in a partially acidic medium (pH 6). While, Tin oxide nanoparticles removed about ~54% at the same conditions. Finally, it is highly recommended to use Copper oxide and Tin oxide nanoparticles as promising adsorbents for heavy metal removal applications.},
year = {2021}
}
TY - JOUR T1 - Facile Preparation of Copper and Tin Oxide Nanoparticles as Efficient Adsorbent of Heavy Metals from Wastewater AU - Ahmed Elsayed Abdelaal AU - Mohamed Abdel-Motaleb AU - Marwa Farouk El Kady AU - Abdel-Rahman Mustafa Hamed Y1 - 2021/03/09 PY - 2021 N1 - https://doi.org/10.11648/j.ijee.20210601.12 DO - 10.11648/j.ijee.20210601.12 T2 - International Journal of Ecotoxicology and Ecobiology JF - International Journal of Ecotoxicology and Ecobiology JO - International Journal of Ecotoxicology and Ecobiology SP - 1 EP - 7 PB - Science Publishing Group SN - 2575-1735 UR - https://doi.org/10.11648/j.ijee.20210601.12 AB - Heavy metal removal from waste water is essential to solve the global water crises. Transition metal oxide nanoparticles are promising candidates for these applications. Herein, Copper oxide and Tin oxide nanoparticles have been prepared via Facile and economic perception method starting from commercial precursors. The obtained nanoparticles were in flack-like shape and spherical shape for Copper oxide and Tin oxide nanoparticles, respectively. All prepared nanoparticles are in crystalline phases, where the prepared Copper oxide and Tin oxide nanoparticles were in monoclinic and tetragonal crystalline phases, respectively. The crystal size of Copper oxide and Tin oxide nanoparticles were 12 nm and 13 nm respectively. Cd and Pb ions were removed from wastewater by the obtained Copper oxide and Tin oxide nanoparticles. The adsorption processes were studied under various parameters, such as; contact time and pH values. The highest removal uptake was about ~99% of Pb ions were recorded for Copper oxide nanoparticles. This uptake process carried out after 30 min in a neutral medium (pH 7). While, Tin oxide nanoparticles removed about ~94% at the same conditions. On the other hand, Copper oxide nanoparticles removed about ~ 57% from Cd ions. This uptake process carried out after 30 min in a partially acidic medium (pH 6). While, Tin oxide nanoparticles removed about ~54% at the same conditions. Finally, it is highly recommended to use Copper oxide and Tin oxide nanoparticles as promising adsorbents for heavy metal removal applications. VL - 6 IS - 1 ER -
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